Ligand Design in Metal Chemistry : Reactivity and Catalysis (2016, Hardcover) DJV, EPUB, TXT
9781118839836 English 1118839838 Ligand Design in Metal Chemistry assembles a collection of cutting-edge chapters documenting the breadth and depth of modern ligand design, in diverse areas such as dinitrogen fixation, polymer synthesis, asymmetric catalysis, cross-coupling and proton reduction chemistry. The concept of ligand design for tuning the structural and reactivity properties of complexes is presented alongside discussions of recent advances and applications to highlight the principles discussed. The book will provide an overview of a variety of approaches to comparable chemistries, while drawing attention to the impact of the ligand environment upon reactivity trends. Topics covered include: * Pincer ligands * Redox non-innocent ligands * Ligand design in modern lanthanide chemistry * New ligation strategies for supporting reactive heterobimetallics and cluster complexes * Tripodal ligands in tuning metal reactivity * Ligand design for catalytic bond activation * Ligand design in polymerization * Ligands in cross-coupling * Carbene ligand design * Supramolecular ligands * Cooperative metal-ligand reactivity * Large biomolecules as chiral ligands * Ligand design in energy catalysis This book will be a valuable reference source for professors, students, researchers and practitioners wishing to learn more about ligand design with applications in organic and pharmaceutical synthesis, as well as polymerization catalysis and applications in energy production., The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.
9781118839836 English 1118839838 Ligand Design in Metal Chemistry assembles a collection of cutting-edge chapters documenting the breadth and depth of modern ligand design, in diverse areas such as dinitrogen fixation, polymer synthesis, asymmetric catalysis, cross-coupling and proton reduction chemistry. The concept of ligand design for tuning the structural and reactivity properties of complexes is presented alongside discussions of recent advances and applications to highlight the principles discussed. The book will provide an overview of a variety of approaches to comparable chemistries, while drawing attention to the impact of the ligand environment upon reactivity trends. Topics covered include: * Pincer ligands * Redox non-innocent ligands * Ligand design in modern lanthanide chemistry * New ligation strategies for supporting reactive heterobimetallics and cluster complexes * Tripodal ligands in tuning metal reactivity * Ligand design for catalytic bond activation * Ligand design in polymerization * Ligands in cross-coupling * Carbene ligand design * Supramolecular ligands * Cooperative metal-ligand reactivity * Large biomolecules as chiral ligands * Ligand design in energy catalysis This book will be a valuable reference source for professors, students, researchers and practitioners wishing to learn more about ligand design with applications in organic and pharmaceutical synthesis, as well as polymerization catalysis and applications in energy production., The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.